A. Reisman, M. Berkenblit, et al.
JES
Reactions of [Formulla Omitted] bipyridine, 2,9-dimethyl-4,7-diphenyl-l,10-phenanthroline) afforded the new compounds [PtMe2X(GeRnX3_n)(N-N)]. The compounds were stable to H2O, alcohol (except for n = 3), pyridine, and PPh3. Compounds with formula [PtMe2X(GeR3)(bpy)] (R = Me, Ph; X = Cl) were not stable in solution and decomposed to PtMe2Cl(CH2Cl)(bpy). Exchange reactions of [PtMe2Cl(MRnCl3-n)(bpy)] with M'RmCl4_m (M, M' = Ge, Sn, Pb) were studied. Reactions with [GeR3Br] resulted in bromine exchange. In the presence of moisture SiRnCl4_n (R = Ph, Me; n = 0, 1,2) reacted with PtMe2(bpy) in CH2C12 to give PtMeCl(bpy). Reactions of CRnC14_n gave the following results (R = Ph, Me; n = 0, 1, 2, 3): Trans oxidative addition occurred with CC14 and CPhCl3. With CPh2Cl2 and CPh3Cl the compound PtMe2Cl2(bpy) was obtained. With CMeCl3 trans addition and further reaction to the vinyl compound [PtMe2Cl(CH2CCl)(bpy)] occurred. No reaction was observed with CMe3Cl. Reactions of CH.C14_. (n = 0, 2, 3) proceeded via trans oxidative addition to [PtMe2Cl-(CHnCl3_n)(bpy)], except in the case of CH2C12 when also cis addition was observed. The rate of the conversion cis → trans was enhanced by added SiPh3Cl. © 1978, American Chemical Society. All rights reserved.
A. Reisman, M. Berkenblit, et al.
JES
Kafai Lai, Alan E. Rosenbluth, et al.
SPIE Advanced Lithography 2007
Thomas E. Karis, C. Mark Seymour, et al.
Rheologica Acta
Andreas C. Cangellaris, Karen M. Coperich, et al.
EMC 2001