Andreas Heise, James L. Hedrick, et al.
JACS
The conformation of amphiphilic 6-arm star block copolymers, with pyrene-tagged polymethyl methacrylate (PMMA) as the hydrophobic inner block attached to a 6-arm initiator and poly(acrylic acid) (PAA) as the hydrophilic outer block, is studied. The conformation of micelles formed from star-like copolymers depends on the selective solvent and can be detected with pyrene probe fluorescence. Concentration dependence studies of polymer in a specific solution indicate the aggregation of star block copolymers and the shift of the polymer concentration at which the excimer intensity is minimized is detected.
Andreas Heise, James L. Hedrick, et al.
JACS
J. Patrick Kampf, Curtis W. Frank, et al.
American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Andreas Heise, Steve Diamanti, et al.
Macromolecules
J. Patrick Kampf, Curtis W. Frank, et al.
American Chemical Society, Polymer Preprints, Division of Polymer Chemistry