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The Journal of Chemical Physics
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The effect of pressure-induced conformational changes on the longitudinal acoustic mode in perfluoro-n-alkanes

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Abstract

An investigation of the longitudinal acoustic mode (LAM) in a series of perfluoro-n-alkanes under pressure has been carried out using Raman spectroscopy in conjunction with a diamond anvil cell. Perfluoro-n-alkanes are shown to undergo a phase transition from a helical to a planar zigzag structure at 5 kbar. This conformational change with pressure results in an abrupt increase in the LAM frequency. Since the chain axis elastic modulus of a planar zigzag molecule is larger than that of a helical one, such a conformational change leads to stiffening of the backbone giving rise to the observed change in the LAM frequency. © 1991 American Institute of Physics.

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The Journal of Chemical Physics

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