Alan J. Hopkins, Leslie V. Woodcock
Journal of the Chemical Society, Faraday Transactions
The shear-flow rheology of the hard-sphere fluid under isokinetic conditions has been investigated by a computer-simulation method. Numerical results for the shear-rate dependence of the tensors of pressure and diffusivity are reported for four dense fluid states, each over a range of shear rate. The shear stress-shear rate flow curves are obtained initially in the isokinetic form by uniform velocity retardation. Results indicate that the onset of a non-linear stress response, and subsequent non-Newtonian phenomena at higher shear rate, can be understood as a shear perturbation of the equilibrium thermodynamic behaviour of the hard-sphere fluid and its phase transitions. The isokinetic flow curve has no direct experimental counterpart. Arguments based upon a renormalisation of the shear-rate scale, however, indicate that the isokinetic flow curve inverts to describe a general laboratory flow curve with the qualitative features of dense colloidal suspensions when seen against the body of experimental evidence. Other common non-Newtonian phenomena, including time-dependent effects (viscoelasticity, thixotropy, rheopexy) and anisotropic effects (normal differences in pressure, diffusivity and granular energy) are also seen in the isokinetic shear-flow model. The isokinetic pressure tensor-shear-rate flow curve may be used to predict experimental laboratory flow curves when the pressures and shear rates are renormalised to a time-scale corresponding to the 'granular temperature' of the experimental system at the same packing fraction.
Alan J. Hopkins, Leslie V. Woodcock
Journal of the Chemical Society, Faraday Transactions
Alan J. Hopkins, Leslie V. Woodcock
Journal of the Chemical Society, Faraday Transactions
Alan J. Hopkins, Leslie V. Woodcock
Journal of the Chemical Society, Faraday Transactions
Alan J. Hopkins, Leslie V. Woodcock
Journal of the Chemical Society, Faraday Transactions