On the electrophoretic term of the limiting law for electrical conductance in solutions

Abstract

The model to which the cluster theory of conductance was applied in an earlier paper is extended to allow for nonpairwise contributions to the interactions among the ions. When the nonpairwise parts of the long-range hydrodynamic interactions are included in the cluster theory calculation, then the electrophoretic term of the limiting law found by Debye, Hückel, and Onsager is recovered.