J.L. Hedrick, R.D. Allen, et al.
Polymer Bulletin
Reduction of phenacyl chloride in DM F containing 1% D2O is electrochemically irreversible, The observed products at the reduction potential are acetophenone plus dimeric product. Recovery of the ketone after short reaction times reveals the presence of considerable H/D exchange of the methylene hydrogens in competition with the reduction reaction. Similarly, in the reduction of 1, 2-diphenylpropanone, which proceeds with asymmetric induction, H/D exchange of the a hydrogen is very important. The exchange process appears to be part of the electrochemical reaction and is associated with the first electron transfer step. © 1977, American Chemical Society. All rights reserved.
J.L. Hedrick, R.D. Allen, et al.
Polymer Bulletin
R.D. Miller, M. Baier, et al.
Pure and Applied Chemistry
J.C. Lacroix, A. Diaz
International SAMPE Electronics Conference 1987
R. Hernandez, A. Diaz, et al.
Journal of Physical Chemistry