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The detailed behavior of the phase transitions was mapped out for the series RNiO3 as a function of the rare earth (R). A sharp insulator-metal transition is observed, which depends strongly on R.Forsmall$R it occurs at a higher temperature than the antiferromagnetic ordering (measured by muon-spin relaxation). By increasing either the temperature or the size of R, an insulator-metal transition is observed, most probably caused by the closing of the charge-transfer gap, induced by increase in the electronic bandwidth. © 1992 The American Physical Society.
Min Yang, Jeremy Schaub, et al.
Technical Digest-International Electron Devices Meeting
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