Exchange coupling in binuclear oxy-bridged iron(III) protoporphyrin IX dimethyl ester

Thomas H. Moss; Henry R. Lillienthal; Charles Moleski; George A. Smythe; Mildred C. McDaniel; Winslow S. Caughey

doi:10.1039/C39720000263

Journal of the Chemical Society, Chemical Communications

Paper

01 Dec 1972

Exchange coupling in binuclear oxy-bridged iron(III) protoporphyrin IX dimethyl ester

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Abstract

μ-Oxo-bis[protoporphyrin IX dimethyl ester iorn(III)] gave magnetic susceptibility data from 1·5 to 293 K which fit a model dimer with strong anti-ferromagnctic exchange coupling (2J 380 K) between highspin iron(III) atoms.

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