Dipole moment and potential energy functions of the X ¹Σ ⁺ and a ¹Σ⁺ states of NaH

Calculated radiative transition probabilities between all vibrational levels in the X 1Σ+ state (υ=0-21) and in the A 1Σ+ state (υ=0-32) of NaH are given. In addition, the calculated spontaneous emission lifetimes for vibrational- rotational levels (J=0,1) and the calculated dipole moments for these same levels are given. The calculations use new hybrid potential energy curves based on Rydberg-Klein-Rees (RKR) and ab initio potential curves. The RKR curve for the X state is new. The calculations use new ab initio dipole moment functions of internuclear distance. © 1984 American Institute of Physics.