Rodney S. Ruoff, J. Tersoff, et al.
Nature
In this letter, the bulk modulus of an individual C60 molecule is calculated in terms of the C,C bond force constant. A range of values for the bulk modulus is obtained with literature values for the force constant. The values obtained all exceed the bulk modulus (441 GPa) of diamond. With a C,C bond force constant equal to that between adjacent carbon atoms in graphite, 7.08 mdyn/Å, a bulk modulus of 903 GPa is obtained. On the basis of a simple composite model it is calculated that single closest-packed C 60 crystals of C60 will have a bulk modulus of roughly 668 GPa under hydrostatic pressures. The calculated bulk modulus for a single C60 "buckyball" therefore suggests the possibility that a C60 crystal could be the most incompressible material known, at a pressure above about 50 GPa.
Rodney S. Ruoff, J. Tersoff, et al.
Nature
Rodney S. Ruoff, Arthur L. Ruoff
Nature
Rodney S. Ruoff, Arthur L. Ruoff
Nature
Xuesong Li, Carl W. Magnuson, et al.
JACS