William G. Van der Sluys, Alfred P. Sattelberger, et al.
Polyhedron
New imide-aryl ether copolymers containing a 1,2,4-triazole heterocyclic unit were prepared, and their structural, mechanical and thermal properties were studied. These copolymers contain an aryl ether 1,2,4-triazole linkage, which was incorporated into a semi-rigid backbone by the reaction of new 1,2,4-triazole diamines with 4,4′-oxydianiline (ODA) and pyromellitic dianhydride (PMDA). The 1,2,4-triazole diamines were prepared through a nucleophilic aromatic substitution reaction of 3,5-bis(4′-fluorophenyl)-4-phenyl-1,2,4-triazole with either 3- or 4-aminophenol in the presence of K2CO3 in a polar aprotic solvent mixture to afford 3,5-bis(3′-aminophenoxyphenyl)-4-phenyl-1,2,4-triazole and 3,5-bis(4′-aminophenoxyphenyl)-4-phenyl-1,2,4-triazole, respectively. The monomers were reacted with PMDA or co-reacted with ODA and PMDA to synthesize the desired poly(amic acid)s. Films were cast and cured at 350°C to effect imidization, producing films with good mechanical properties. © 1993.
William G. Van der Sluys, Alfred P. Sattelberger, et al.
Polyhedron
Arvind Kumar, Jeffrey J. Welser, et al.
MRS Spring 2000
William Hinsberg, Joy Cheng, et al.
SPIE Advanced Lithography 2010
Eloisa Bentivegna
Big Data 2022