Wesam Alramadeen, Yu Ding, et al.
IISE Transactions on Healthcare Systems Engineering
The photolysis of 2-cyanofuran in alcohols yields 1-alkoxy-2-cyanocyclopropane-3-carboxaldehydes as the major products, which rearrange thermally to trans-2-alkoxy-3-cyano-2,3-dihydrofurans and small amounts of cis-isomers. Thermal mutual rearrangements between trans- and cis-2- alkoxy-3-cyano-2, 3-dihydrofurans were studied. Liquid phase thermal addition of alcohols in a temperature range between 100° and 200° yields 1-alkoxy-1-(2-furan)-methylenimines, which rearrange photochemically to 2-furyl-methylamino-ketone in case of the methoxy derivative. 3-Cyano-furan does not yield photoaddition or thermal addition products. The different behaviors of 2- and 3-substituted furans are discussed. © 1973.
Wesam Alramadeen, Yu Ding, et al.
IISE Transactions on Healthcare Systems Engineering
Victor W. L. Ng, Julian M. W. Chan, et al.
Advanced Drug Delivery Reviews
Andreana Gomez, Sergio Gonzalez, et al.
Toxics
Shengping Liu, Baoyao Zhou, et al.
AMIA ... Annual Symposium proceedings / AMIA Symposium. AMIA Symposium