Soft x-ray diffraction of striated muscle
S.F. Fan, W.B. Yun, et al.
Proceedings of SPIE 1989
Using density-functional theory as implemented in the projector- augmented wave method, we have calculated structures, energy levels, structures of the protonated forms, and proton affinities of the phosphanes PH3, PF3, P(CF3)3, PMe3, P(NMe2)3, P(C6H5)3, P(p-C6H4OMe2)3, and P(p-C6H4NMe2)3. The donor strengths of the phosphanes are discussed in terms of lone-pair energies and proton affinities. The influence of the donor ability of the phosphane ligands on the protonolytic cleavage of the metal-carbon bond in [NiCl(CH2CH2NH3)(PR3)2]+ complexes has been studied. A linear relationship between the lone-pair energies of the phosphanes and the activation barrier has been established. (C) 2000 Elsevier Science B.V.
S.F. Fan, W.B. Yun, et al.
Proceedings of SPIE 1989
Sang-Min Park, Mark P. Stoykovich, et al.
Advanced Materials
Andreas C. Cangellaris, Karen M. Coperich, et al.
EMC 2001
Ellen J. Yoffa, David Adler
Physical Review B