Daxiang Gui, Xing Dai, et al.
Inorganic Chemistry
When exposed to water, the two-dimensional uranyl-organic layered compound [(CH3)2NH2][(UO2)(BCPBA)]·2DMF·H2O (H3BCPBA = 3,5-bis (4′-carboxylphenoxy) benzoic acid) gradually undergoes a complete single-crystal-to-single-crystal phase transition to [(CH3)2NH2][(UO2)(BCPBA)]·3.4H2O, resulting in an enhanced ligand-ligand interaction between the adjacent layers. This process gives rise to initial quenching of the uranyl photoluminescence followed by subsequent recovery of the photoluminescence with a much elevated intensity, as a unique case of aggregation-induced emission in an extended solid system, further confirmed by DFT analysis on bonding.
Daxiang Gui, Xing Dai, et al.
Inorganic Chemistry
Xuanchu Ge, Xing Dai, et al.
Inorganic Chemistry
Yuanchao Zhang, Jingquan Liu, et al.
ACS Nano
Tao Zheng, Zaixing Yang, et al.
Nature Communications