Ronald Troutman
Synthetic Metals
Ligand-stabilized copper(I) hexafluoroacetylacetonate complexes display varying degrees of stability to oxidation and thermal decomposition. In an effort to understand the nature of the copper-alkene bond in these complexes better, 1H and 13C nuclear magnetic resonance spectra were obtained and compared to the spectra of the free alkene. In accord with Dewar-Chatt-Duncanson theory, the extent of π and σ bonding contributions can be qualitatively determined by the observed chemical shift changes upon complexation of the alkene to the copper(I) center. © 1992.
Ronald Troutman
Synthetic Metals
L.K. Wang, A. Acovic, et al.
MRS Spring Meeting 1993
Revanth Kodoru, Atanu Saha, et al.
arXiv
R.J. Gambino, N.R. Stemple, et al.
Journal of Physics and Chemistry of Solids