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Chemical Physics Letters
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EPR parameters and ionic-covalent transition in solids

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Abstract

The anomalous change of EPR parameters of half-filled 3d ions in various compounds with the covalency parameter is discussed in view of the recently proposed ionic-covalent transition. It is pointed out that the parameters g, a and D are sensitive to the long-range interaction bringing up the transition, whereas A reflects the local cluster bonding properties. © 1970.

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Chemical Physics Letters

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