J.M. Hicks, K. Kemnitz, et al.
Journal of Physical Chemistry
The yield and final-state distributions in translational and internal degrees of freedom have been established for NO molecules desorbed from a Pd(111) surface by 200-fs pulses of 2.0-eV photons. Among the significant characteristics of the desorption process are the large cross section and the high vibrational energy content (Tv>2000 K) of the desorbed molecules. A comparison with the behavior for nanosecond laser pulses indicates that a new desorption mechanism, distinct from either conventional thermal or photochemical processes, is operative in this regime. © 1990 The American Physical Society.
J.M. Hicks, K. Kemnitz, et al.
Journal of Physical Chemistry
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Materials Research Society Symposium - Proceedings
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SPIE OE/LASE 1994
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