Controllable valley splitting in silicon quantum devices

Silicon has many attractive properties for quantum computing, and the quantum-dot architecture is appealing because of its controllability and scalability. However, the multiple valleys in the silicon conduction band are potentially a serious source of decoherence for spin-based quantum-dot qubits. Only when a large energy splits these valleys do we obtain well-defined and long-lived spin states appropriate for quantum computing. Here, we show that the small valley splittings observed in previous experiments on Si-SiGe heterostructures result from atomic steps at the quantum-well interface. Lateral confinement in a quantum point contact limits the electron wavefunctions to several steps, and enhances the valley splitting substantially, up to 1.5 meV. The combination of electrostatic and magnetic confinement produces a valley splitting larger than the spin splitting, which is controllable over a wide range. These results improve the outlook for realizing spin qubits with long coherence times in silicon-based devices. © 2007 Nature Publishing Group.