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Publication
Electrochimica Acta
Paper
Conformational constraints in the reactions of surface bonded intermediates
Abstract
The dimerization process resulting from electrochemically generated pyrazoline radical cations is found to be less important for surface bonded derivatives than for dissolved species. Furthermore, the fraction of dimer produced from the surface bonded derivatives depends on the potential sweep rate. The interpretation given to these results is that the motion of the surface molecules is slow compared to the charge transfer process. © 1981.