N.O. Lipari, M.J. Rice, et al.
International Journal of Quantum Chemistry
A phase transition starting at 84 K and indicated by a marked color change of the sample has been found in the organic insulator tetrathiafulvalene- chloranil. Optical, infrared, and Raman measurements indicate that this is a reversible transition from a nominally neutral (N) solid to a nominally ionic (I) salt. Surprisingly, the N-I transition is not first order, but occurs over a broad temperature region (∼30 K), in which there is a coexistence of N and I molecules. © 1981 The American Physical Society.
N.O. Lipari, M.J. Rice, et al.
International Journal of Quantum Chemistry
T. Penney, M.W. Shafer, et al.
Physical Review B
R. Bruinsma, Per Bak, et al.
Physical Review B
P. Batail, L. Ouahab, et al.
Solid State Communications