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Chemical Physics Letters
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Activation energies of charge transport in doubly-doped polymers: polarons and disorder

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Abstract

We have measured the thermal activation energies of charge carrier mobilities in polycarbonate doped with two similar hydrazone transport molecules. The results are consistent with polaron formation contributing a major fraction of the activation energy. The observations cannot be reconciled with the simple application of a model based on site energy disorder, although some type of disorder is necessary to account for the observed dispersive behavior and the anomalous broadening of the transients. © 1992.

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Chemical Physics Letters

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