The isomerization of optically-active propargyl alcohols to terminal acetylenes.

M.Mark Midland; Ronald L. Halterman; Charles A. Brown; Angela Yamaichi

doi:10.1016/S0040-4039(01)82095-5

Tetrahedron Letters

Paper

01 Jan 1981

The isomerization of optically-active propargyl alcohols to terminal acetylenes.

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Abstract

The isomerization of optically-active secondary propargyl alcohols, RCHOHCC(CH2)nCH3, to terminal acetylenic alcohols, RCHOH(CH2)n+1 C=CH, by potassium 3-aminopropylamide (KAPA) proceeds without loss of configuration at the hydroxy center. © 1987.

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