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Generation and pyrolysis of a cyclopropyl substituted cyclopentadiene: A potential source of unsaturated annelated cyclopentanones
Abstract
The tertiary allylic alcohol (2) is readily dehydrated by catalytic amounts of non-aqueous acid to the cyclopentadiene derivative (3), which is subsequently regiospecifically transformed to the vinyl sulphide (6) by pyrolysis.
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