J.P. Chaminade, A. Garcia, et al.
Journal of Crystal Growth
The polarized emission spectra of melt and vapor grown single crystals of carefully purified 9-cyanoanthracene (9-CNA) are reported. This materials has a quasi one-dimensional structure with molecules stacked along the c-axis. In crystals previously unirradiated at room temperature, the emission is excimer-like with a double peak (550 nm, E⊥c) and (525 nm, E|c) at 2 K, and a single peak at 300 K (588 nm, E, |c). Exposure to UV radiation at room temperature induces fluorescence associated with the production of photodimers. At 2 K this fluorescence is highly structured and coexists with excimer emission. It also extends to higher energies than the origin of the exciton band of the first singlet, supporting a model in which this component of the fluorescence arises from 9-CNA molecules separated from bulk by a matrix of photodimers. The photoproduct thus acts somewhat like a Shpol'skii matrix for these unreacted molecules. © 1976.
J.P. Chaminade, A. Garcia, et al.
Journal of Crystal Growth
Kevin Ashley, Frederick Weinert, et al.
Journal of Physical Chemistry
V. Novotny, Ingo Hussla, et al.
The Journal of Chemical Physics
D. Boye, R.M. Macfarlane
Physical Review B - CMMP