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Differential radical cation stability from the cis- and trans-cyclodiphospha(III)azane derivatives
Abstract
The electrochemical oxidation reactions of cis-and trans-1,3-di-isopropyl- 2,4-bis(di-isopropylamino)-cyclodiphospha(III)azane isomers are quite different; only the trans-(1) isomer undergoes a one-electron oxidation reaction to produce a stable radical cation.
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