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Chemical Physics Letters
Paper

A van der waals theory with quartic density gradients

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Abstract

Functional methods show that biphasic mixtures of rods and solvent have interfacial free energies quartic in the density gradient in contrast to the quadratic van der Waals theory. The result is novel because there is more than one order parameter and because the coupling is via the distribution functions. © 1982.

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Chemical Physics Letters

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